脲醛樹(shù)脂膠黏劑
1 什么是脲醛樹(shù)脂黏膠劑
脲醛樹(shù)脂膠黏劑,具有工藝簡(jiǎn)單、原料廉價(jià)、粘度強(qiáng),及無(wú)色透明等優(yōu)點(diǎn),在膠合板、刨花板、中密度纖維板、人造板材的生產(chǎn),以及室內(nèi)裝修行業(yè)中被廣泛用到,它是一種開(kāi)發(fā)比較早的熱固性高分子膠黏劑。
2 脲醛樹(shù)脂黏膠劑作用
脲醛樹(shù)脂膠黏劑已為我國(guó)人造板生產(chǎn)中主要用到的膠種,少部分會(huì)用在生產(chǎn)模塑粉中,此外,還會(huì)用于裝飾用層壓板、紙張、紡織加工,有的會(huì)作為處理劑之用。它具有以下幾項(xiàng)重要作用:
1.尿素與甲醛的摩爾比值越小,那么游離的羥甲基也將越小,而固化樹(shù)脂的耐水性也越好。樹(shù)脂固化速度越快,那么樹(shù)脂的穩(wěn)定性將越好,樹(shù)脂中游離甲醛的含量也越低。
2.介質(zhì)為堿性時(shí),主要產(chǎn)生加成反應(yīng)生成羥甲脲;介質(zhì)為酸性時(shí),主要產(chǎn)生縮合反應(yīng)生成脲基羥甲醛。其中,堿性介質(zhì)中的反應(yīng),縮聚反應(yīng)比較慢,而在酸性介質(zhì)中,如果油漆PH值非常低,則縮聚反應(yīng)會(huì)相當(dāng)快,控制不好,將會(huì)產(chǎn)生過(guò)早凝膠和固化的可能。
3.尿素中的硫酸鹽要控制好,含量太高,反應(yīng)液升溫會(huì)很快,令反應(yīng)介質(zhì)的PH值降低的極限值更低,從而使反應(yīng)液快速失去透明性而成為乳白色。硫酸鹽的含量太高會(huì)降低樹(shù)脂儲(chǔ)存中的膠合過(guò)程,硫酸鹽的含量不可比0.01%高。而尿素中的縮二脲明顯會(huì)影響膠黏劑儲(chǔ)存中的粘接強(qiáng)度,需要控制在0.8%以下。
4.脲醛樹(shù)脂的縮聚反應(yīng)溫度,通常是在70-100攝氏度之間,酸性介質(zhì)中過(guò)高的溫度會(huì)令反應(yīng)更為劇烈,產(chǎn)品的粘度也因此過(guò)大,甚至有凝膠的作用。
5.一些有著特殊要求的脲醛樹(shù)脂,它的反應(yīng)時(shí)間是特定的,通常是在120-150分鐘,反應(yīng)時(shí)間太短,縮聚反應(yīng)會(huì)不完全,樹(shù)脂含固量降低,游離甲醛量變高,膠層機(jī)械強(qiáng)度降低;膠層機(jī)械強(qiáng)度降低,反應(yīng)時(shí)間過(guò)長(zhǎng),那么樹(shù)脂的聚合度增高,分子量過(guò)大,粘度變大,水溶性變小,儲(chǔ)存穩(wěn)定性將下降。
3 脲醛樹(shù)脂膠黏劑有什么特點(diǎn)
優(yōu)點(diǎn):固化前具有水溶性,所以對(duì)于很多基材使用都非常方便,而且還可與其他的許多材料搭配使用,也可任意使燃料和顏料著色,耐溶性好,硬度高。
缺點(diǎn):固化之時(shí)容易收縮,膠層易出現(xiàn)裂縫,耐水性不好。含有游離甲醛,使用脲醛樹(shù)脂及含有脲醛樹(shù)脂膠黏劑制備的產(chǎn)品中,會(huì)有甲醛的臭味產(chǎn)生,這種強(qiáng)烈刺激性味道會(huì)刺激人的視粘膜、鼻粘膜和上呼吸道,對(duì)人體健康有非常大的威脅。
4紅蘋(píng)果書(shū)柜產(chǎn)品效果圖
5鋼質(zhì)防火門(mén)安裝
鋼制防火門(mén)在安裝過(guò)程中,考慮到門(mén)框的彎曲變形這個(gè)問(wèn)題,要在門(mén)框?qū)挾确较蛴媚捐手纹饋?lái),門(mén)框下腳埋入地面下20mm,再將門(mén)框與墻體上的預(yù)埋件焊接。然后在門(mén)框上角的墻上開(kāi)洞,灌注水泥、砂、膨脹珍珠巖(1:2:5)的混凝土,等混凝土凝固后就可以使用。
國(guó)家標(biāo)準(zhǔn)對(duì)防火門(mén)各搭接處的縫隙大小有明確要求:對(duì)鋼質(zhì)防火門(mén),要求其扇與門(mén)框搭接不得小于10mm,扇與門(mén)框之間的兩側(cè)縫隙不得大于4mm。防火門(mén)安裝完閉以后的縫隙不能過(guò)大,否則防火門(mén)的密閉性能難以保證,也難以體現(xiàn)其在火災(zāi)條件下抑制火災(zāi)及煙氣蔓延作用。
因此,防火門(mén)安裝的留縫寬度必須嚴(yán)格控制。根據(jù)這些標(biāo)準(zhǔn)規(guī)范安裝,能在一定程度上保證防火門(mén)的有效作用,消費(fèi)者在雇傭施工單位時(shí)一定要在一旁監(jiān)督,防止他們偷工減料等問(wèn)題的發(fā)生,這樣才能讓防火門(mén)不會(huì)在發(fā)生火災(zāi)時(shí)造成人員的傷亡。
6金屬軟管品牌
推薦以下金屬軟管品牌,排名不分先后,僅供參考。
1、ATTS沃茨:1874年成立,美國(guó)著名品牌,其產(chǎn)品在全世界都享有極高聲譽(yù)。
2、愛(ài)索爾:技術(shù)卓越,產(chǎn)品質(zhì)量享譽(yù)全球。
3、聯(lián)塑:軟管十大品牌。
4、鵬程:國(guó)內(nèi)外著名汽車(chē)軟軸軟管配套商。
5、春光:軟管十大品牌,國(guó)家級(jí)高新技術(shù)企業(yè)。
6、百順:1990年成立,在同業(yè)中知名度高,是國(guó)內(nèi)金屬波紋涵管大型制造企業(yè)。
7、天孚:日本品牌,技術(shù)先進(jìn),產(chǎn)品暢銷(xiāo)國(guó)內(nèi)外各地。
8、凱鴻:1979年創(chuàng)建,是一家集金屬軟管、鎧裝光纜等應(yīng)用產(chǎn)品的研發(fā)、生產(chǎn)、營(yíng)銷(xiāo)及服務(wù)于一體的大型企業(yè)。
9、菲時(shí)特:亞洲最大的金屬軟管生產(chǎn)企業(yè)之一,國(guó)家級(jí)高新技術(shù)企業(yè)。
10、京生:十大軟管品牌,產(chǎn)品質(zhì)量頗受消費(fèi)者信賴。
7膩?zhàn)臃塾卸締?
正規(guī)的膩?zhàn)臃凼菬o(wú)味無(wú)毒的,用戶可放心的使用,但是這里衷心的提醒消費(fèi)者,在對(duì)于膩?zhàn)臃鄣馁?gòu)買(mǎi)中,一定要選擇質(zhì)量有所保證以及知名度高的品牌進(jìn)行購(gòu)買(mǎi),以避免購(gòu)買(mǎi)到假冒偽劣產(chǎn)品,從而影響到自身的身體健康。
8膩?zhàn)臃蹆r(jià)格
由于市場(chǎng)上的膩?zhàn)臃鄯N類(lèi)型號(hào)眾多,所以其價(jià)格也是不確定的,一般在市場(chǎng)上的膩?zhàn)臃鄣膬r(jià)格在1500-2200元一噸左右,具體的價(jià)格消費(fèi)者可前往當(dāng)?shù)氐慕ú纳虉?chǎng)進(jìn)行詢價(jià)。
9雙人折疊床
雙人折疊床標(biāo)準(zhǔn)規(guī)格為2000*1800mm或2000*1500mm。
然而在實(shí)際生產(chǎn)中受折疊床款式的影響,雙人床寬度的尺寸維持在1000mm到1900mm之間,床度保持在1900mm到2100mm之間。
雙人折疊床多為沙發(fā)床形式出現(xiàn),便攜式戶外折疊床雙人規(guī)格的比較少。雙人折疊床的價(jià)格受材質(zhì)的影響相差甚大,從幾百元到上千的都有。
10實(shí)木折疊床
實(shí)木折疊床兼具了實(shí)木床和折疊床的優(yōu)點(diǎn):
從材質(zhì)上講:實(shí)木折疊床多采用松木或者楠竹制作而成,堅(jiān)固耐用,容易保養(yǎng),健康環(huán)保無(wú)污染。
從功能上講:實(shí)木折疊床可以折疊收納,方便了小空間居室擁擠的難題,同時(shí)也可以作為來(lái)客招待的床,不用時(shí)收起來(lái)即可,免去了設(shè)置客房的浪費(fèi)。
從外形上講:實(shí)木折疊床相比于普通的鋼架折疊床要美觀的多,具有一定裝飾性。
11多功能折疊床
多功能折疊床是一種多用的家具,一般來(lái)說(shuō)是坐臥兩用的,使用該折疊床時(shí)可以根據(jù)需要來(lái)設(shè)定床架放下來(lái)的角度,可以變成椅子沙發(fā)或者床。
現(xiàn)有一種新型多功能折疊床,在不使用折疊床時(shí)可以隱藏在柜子里面的,即翻上床架就是個(gè)柜子,放下床架就變成一張舒適的床鋪。
12兒童折疊床
兒童床折疊床價(jià)格便宜、使用簡(jiǎn)單、便于收納,被許多家長(zhǎng)選購(gòu)作為孩子的備用床,在孩子還小的時(shí)候使用折疊床,孩子大了再使用常規(guī)的床鋪。
需要注意的是因?yàn)閮和谏L(zhǎng)發(fā)育期,睡折疊床其實(shí)不利于孩子的骨骼發(fā)育,因此不建議讓孩子長(zhǎng)期睡折疊床。
在購(gòu)買(mǎi)兒童折疊床的時(shí)候要注意是否遵守以下相關(guān)的安規(guī)標(biāo)準(zhǔn):
一、美國(guó)標(biāo)準(zhǔn)F406-11版,非標(biāo)準(zhǔn)尺寸童床/游戲床的標(biāo)準(zhǔn)消費(fèi)品安全規(guī)范。
二、歐洲標(biāo)準(zhǔn)EN716-08版,家用童床和折疊床。
第一部分:安全要求;
第二部分:測(cè)試方法。
三、歐洲標(biāo)準(zhǔn)EN12227-2010版,家用游戲床的安全要求和測(cè)試方法。
四、國(guó)家行業(yè)標(biāo)準(zhǔn)QB 2453.1-99和QB 2453.2-99版,家用小床安全要求的測(cè)試方法。
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